Suatu larutan dibuat dengan mencampurkan 200 ml larutan CH3COOH 0,1 M dengan 100 ml larutan CH3COONa 0,1 M. jika diketahui Ka = 10-5. berapa pH larutan tersebut…

suatu larutan dibuat dengan mencampurkan 200 ml larutan CH3COOH 0,1 M dengan 100 ml larutan CH3COONa 0,1 M. jika diketahui Ka = 10-5. berapa pH larutan tersebut…

Jawaban yang benar adalah pH = 5 – log 2.

Pembahasan :
Campuran kedua larutan diatas akan membentuk larutan penyangga. Larutan penyangga atau buffer atau dapar merupakan larutan yang dapat mempertahankan pH dengan sedikit penambahan asam, basa atau air (pengenceran).

– Larutan penyangga asam
Asam lemah dengan garamnya (basa konjugasinya), contoh CH3COOH dan CH3COONa.

Rumus :
[H+] = Ka × ([asam]/[garam])
atau
[H+] = Ka × (mol sisa asam/mol garam)
pH = -log [H+]

Keterangan :
[H+] = konsentrasi ion H+ (M)
Ka = tetapan kesetimbangan asam
Ma = konsentrasi asam (M)

Penyelesaian :
Mol CH3COOH = [CH3COOH] × V CH3COOH
= 0,1 M × 200 mL
= 0,1 M × 0,2 L
= 0,02 mol

Mol CH3COONa = [CH3COONa] × V CH3COONa
= 0,1 M × 100 mL
= 0,1 M × 0,1 L
= 0,01 mol

[H+] = Ka CH3COOH × (mol CH3COOH/mol CH3COONa)
= 10^-5 × (0,02 mol/0,01 mol)
= 10^-5 × 2
= 2 × 10^-5 M

pH = –log [H+] = –log (2 × 10^-5)
= 5 – log 2

Jadi, pH campuran diatas adalah 5 – log 2.

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